Efforts include examining novel reagents for the flotation of Rare Earth Minerals (REMs). For this paper, research results on a collector, salicyl hydroxamic acid (SHA), are presented. Various REMs were examined and include the rare earth oxides (REOs), carbonates (RECs), and phosphates (REPs) of a suite of Rare Earth Elements (REEs).
A review of reagents applied to rare-earth mineral flotation. Adv Colloid Interface Sci, 279 (2020), Article 102142. View in Scopus Google Scholar. 63. ... Improving rare-earth mineral separation with insights from molecular recognition: functionalized hydroxamic acid adsorption onto bastnasite and calcite. Langmuir, 38 ...
Geology, deposit types, and ore minerals. There are more than 200 minerals that contain REE. 7,8 The most common rare-earth minerals are monazite and bastnäsite (Figure 1a–b and Table II).Monazite exists as a group of arsenates, phosphates, and silicates, but the primary REE-bearing monazite is a complex phosphate. 5 Bastnäsite, also known as …
Bastnasite Flotation As the primary rare earth mineral at two of the world's largest rare earth mines (Mountain Pass, CA and Bayan Obo, China) bastnasite has been the main focus of rare earth flotation research for some time. During this time, a variety of collectors for the flotation of rare earths bastnasite have been investigated ...
DOI: 10.1016/j.cis.2020.102142 Corpus ID: 214787347; A review of reagents applied to rare-earth mineral flotation. @article{Marion2020ARO, title={A review of reagents applied to rare-earth mineral flotation.}, author={Christopher Marion and Ronghao Li and Kristian Edmund Waters}, journal={Advances in colloid and interface science}, year={2020}, volume={279}, …
Potential ionic-liquid (IL) collector for flotation of rare earth bearing minerals. Superior selectivity of IL vs. hydroxamic-acid collectors for rare earth mineral flotation. Nature of IL interaction studies by zeta potential, FTIR and XPS measurements. IL chemisorbed on RE minerals via its anion while cation involved in weaker ...
1. Introduction. The rare earth elements (REE) have been applied in many high-end technology applications, including magnets, catalysts, hydrogen storage, electronic devices, ceramics, and polishing powders. 1 While more than 250 rare earth minerals (REM) have been discovered, 2 the majority of the world's REE (particularly LREE) are sourced from the …
There are fewer studies on flotation of rare earth minerals such as xenotime or some new complex ore reserves compared to bastnäsite and monazite flotation. An important example of these new complex ore reserves is the previously mentioned Nechalacho deposit which bastnäsite, synchysite, allanite, and monazite are found as light REE minerals ...
Pradip (1981) The surface properties and flotation of rare-earth minerals. PhD Dissertation Univ of California Berkeley 211 pp. Fuerstenau DW, Pradip, Khan LA, Raghavan S (1983) An alternate reagent scheme for the flotation of Mountain Pass rare-earth ore. Proc. XIV International Mineral Processing Congress, Toronto, Canada IV (6):1–12
This study presented the first in a series of investigations currently underway to develop efficacious, cost-effective, and benign processing opportunities to produce rare earth elements (REE)–rich concentrate from an Australian complex low–grade saprolite ore [1.14% total rare earth oxides (TREO) grade], which is primarily exploited for its gold and copper values.
This enables more efficient flotation of the rare earth minerals. Fig. 2.13. Low magnetic separation, high magnetic separation, flotation process. Full size image. Sodium silicate is used as a depressant and H 2 O 5 as collector. H205 is a kind of hydroxamic acid with amide as the polar end and aromatic hydrocarbon as the non-polar end.
Common collectors for rare earth mineral (REM) flotation, which include carboxylates and hydroxamates, face problems such as being non-selective and sensitive to impurity ions. A type of ionic liquid (IL), tetraethylammonium mono-(2-ethylhexyl)2-ethylhexyl phosphonate ([N 2222][EHEHP]), has been investigated previously for rare earth elements …
This study presented the first in a series of investigations currently underway to develop efficacious, cost-effective, and benign processing opportunities to produce rare earth elements (REE)–rich concentrate from an Australian complex low–grade saprolite ore [1.14% total rare earth oxides (TREO) grade], which is primarily exploited for its gold and copper values. …
Rare earth elements (REEs) found in coal are in the form of minerals, ion-adsorbed onto clay surfaces or inner layers, or organically bound. Rare earth minerals such as monazite exist in coal and have grain sizes smaller than 5 µm. In this study, froth flotation was successful in concentrating rare earth minerals existing in a thickener underflow material …
EDTA, a common complexing agent with a strong ability to form complexes with calcium ions, is utilized in rare earth ore flotation to effectively depress alkaline earth minerals like fluorite [123]. The mechanism involves EDTA chemically dissolving the collector adsorbed on gangue minerals and forming Ca-EDTA complexes on the mineral surface.
The primary rare earth minerals processed commercially are bastnäsite, monazite, and xenotime. One of the primary separation techniques used to beneficiate rare earth minerals is froth flotation because it allows the processing of a relatively wide range of fine particle sizes, can be tailored to the unique mineralogy of a specific deposit and has been successfully used …
minerals that contain rare earth elements comprised of cerium, lanthanum, praseodymium, and other light rare earth elements. The focus of this research was to find a novel collector that ... A rougher flotation experiment produced a rare earth oxide grade and recovery of 41% and 78%, respectively with a 91.5% rejection of calcite. This is
A large bastnasite deposit was discovered at Mountain Pass, Calif. Subsequent development of the deposit made the United States the world's largest source of rare-earth minerals. Since then, bastnasite, a fluocarbonate of the cerium-group metals, REFCO3, has replaced monazite as the principal source of rare earths; in 1978 it accounted for more than …
Eudialytes are a nonconventional source for rare earth elements (REE). As the total REE content of eudialytes is relatively low, high-grade mineral concentrates have to be produced. The applicability of magnetic separation and direct selective flotation for the processing of eudialyte ore from Norra Kärr (Sweden) was tested. The eudialyte in the used …
Rare earth elements are in high demand in the USA. Bastnaesite, a rare earth fluorocarbonate containing primarily cerium and lanthanum, is one of the most abundant sources of rare earths in the USA. This research was completed using the ore from Mountain Pass, which is the largest rare earth mine in the USA. This research, resulting in a current patent …
The flotation process is considered one of the most important techniques to separate rare earth minerals from associate minerals and is commonly applied to the beneficiation of rare earth ores. It is worth mentioning that this separation method is used to separate minerals by exploiting the differences in their surface wettability [ 12, 24 ].